The Waterborne Symposium

Abstract
Challenges in Formulating Water Based Clear Sealers for Concrete

Solventbased acrylic sealers for concrete have been used for many years and are considered by many to be the performance standard for sealers.  The primary drawback to these solvent based sealers is that they are very high in volatile organic compounds (VOCs), and industry regulations are driving sealer manufacturers to evaluate low VOC, waterborne alternatives.  Due to differences in their film formation mechanisms, there are differences in performance between most waterborne and solventbased sealers.  Despite these differences, the use of a novel polymer technology has yielded waterborne sealers with an improved balance of properties that is commercially acceptable for today’s concrete sealers.  Performance data of sealers formulated with this new polymer and evaluated against conventional concrete sealers will be presented.

Abstract
Microfibrillated Cellulose – The Effect of a Novel and Renewable Multifunctional Additive on Common Waterborne Coating Issues
Co-author: Ali Moosavifar

There is a growing interest to move towards waterborne systems in the coatings industry due to environmental and occupational health reasons. However, the change is not always straightforward and often new technologies are required to obtain the same performance as with solvent borne systems.
Microfibrillated cellulose (MFC), a value-added and multifunctional product made of cellulose, consisting of fibers with lateral dimensions in the nanoscale and lengths up to micron scale. The main characteristics of this unique fiber structure is its resembling of both water soluble polymers and insoluble additives, leading to a versatile and efficient alternative to technologies currently available. The high inertness, compatibility and stability of MFC is opening up new possibilities for waterborne paints and coatings, especially for the more demanding formulations. MFC secures high viscosity at rest, giving good stability, as well as offering shear thinning behavior and rapid viscosity build-up, which prevents sag during application. The aim of this work was to evaluate the effect of MFC to the rheological behavior of the coating formulation as well
as to the final film properties. Waterborne exterior flat paint, based on a blend of acrylic and vinyl acrylic binderswas used to investigate the effect of MFC on prevention of syneresis as well mud cracking of the  coating. Deep base acrylic paint was used to evaluate the effectiveness of MFC to prevent viscosity loss on tinting, color float and sagging. We will demonstrate how MFC can solve typical challenges in waterborne high quality architectural paints and coatings regarding, for example, mud-cracking, viscosity loss, sagging and sprayability. This study will widen the understanding of the opportunities of MFC on coatings but as well as to demonstrate its potential on other fields such as adhesives and in demanding formulations. Understanding the effect of these novel hybrid type of multifunctional additives on the formulation as well as on the film properties, is essential.

Abstract
Low VOC Waterborne Epoxy Floor Coatings

Over the past 30 years, the popularity and use of waterborne (WB) coatings has increased steadily, driven primarily by the desire to reduce the presence of volatile organic compounds (VOCs) and their impact on human health and the environment.  Inherently, WB coatings are low-toxic, low odor, eco-friendly, and easy to handle.  Through new WB epoxy technology and advancements in the past 10 - 20 years, WB epoxy coatings maintain all the performance strengths of traditional high VOC solventbased coatings and high solids systems, making them suitable for commercial and industrial use.  This paper describes some of our work in developing WB coatings designed for floor applications in warehouses, garages, hospitals, and light manufacturing plants.  We have developed high film build, self-leveling coatings, and satin gloss roller coatings at very low or even near zero VOC levels.  Various performance aspects of these experimental WB epoxy floor coatings will be discussed, including dry time, Shore D hardness, abrasion resistance, and compressive strength.  Starting formulations and application procedures will also be described.